CONJUGATED REACTIONS IN CHEMISTRY AND BIOLOGY IN THE CONTEXT OF MODERN IDEAS

Description

Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced; the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under-­researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered. The ensemble of reactions is self-organized through the intermediary of general highly active substances. These processes may be accelerated and effectively implemented with the help of catalysts similar to processes, which take part in the living systems. Self-organization of an ensemble of reactions capable of being intensified or weakened and, therefore, inducing chemical interference, may be suggested as the basis for the principle of organization of many enzymatic ensembles.